Nitrogen isotopic evidence for deglacial changes in nutrient supply in the eastern Equatorial Pacific

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doi: 10.1029/2008PA001702
Author(s): Robinson, R. S.; Martinez, P.; Pena, L. D.; Cacho, I.
Author Affiliation(s): Primary:
University of Rhode Island, Graduate School of Oceanography, Narragansett, RI, United States
Université Bordeaux I, France
University of Barcelona, Spain
Volume Title: Paleoceanography
Source: Paleoceanography, 24(4). Publisher: American Geophysical Union, Washington, DC, United States. ISSN: 0883-8305 CODEN: POCGEP
Note: In English. 61 refs.; illus., incl. sketch maps
Summary: The Eastern Equatorial Pacific (EEP) is a high nutrient-low chlorophyll region of the ocean. Downcore nitrogen isotope records from the EEP have been previously interpreted as a direct reflection of changes in nutrient consumption. However, the observed changes in sedimentary δ15N since the last glacial maximum have no coherent relationship with export productivity or an inferred variation in the iron-to-nitrate ratio of the surface waters. Rather, downcore N isotope records in the EEP strongly resemble changes in the extent of water column denitrification as recorded in nearby sedimentary δ15N records along the western margin of the Americas. This similarity is attributed to the overprinting of the N isotopic composition of nitrate in the EEP through the advection of nitrate westward from the margins in the subsurface. A local nitrogen isotope record of changes in the degree of nutrient consumption is extracted from the bulk sedimentary record by subtracting two different sedimentary δ15N records of denitrification changes from two new EEP δ15N records (TR163-22 and ODP Site 1240). The denitrification records used are from 1) the Central American margin (ODP Site 1242) and 2) the South American margin (GeoB7139-2). The degree of consumption in the surface waters declines rapidly from elevated values during the last glacial maximum to a pair of minima around 15 and 11-13 ka, and finally it increases into the Holocene. The derived EEP nitrogen isotope record indicates that the regional peak in export productivity occurred when the supply of nutrients exceeded the apparently high demand. The influx of nutrients during the deglaciation is attributed to the resumption of intense overturning in the Southern Ocean and the release of sequestered CO2 and nutrient-rich, O2 poor waters from the deep ocean. This has important implications for understanding the glacial-interglacial scale variation in intermediate water suboxia and water column denitrification.
Year of Publication: 2009
Research Program: ODP Ocean Drilling Program
Key Words: 02 Geochemistry; 24 Surficial Geology, Quaternary Geology; Cenozoic; Deglaciation; East Pacific; Equatorial Pacific; Isotope ratios; Isotopes; Leg 202; Marine environment; N-15/N-14; Nitrogen; North Pacific; Northeast Pacific; Nutrients; ODP Site 1240; ODP Site 1242; Ocean Drilling Program; Pacific Ocean; Paleoclimatology; Paleoecology; Paleoenvironment; Panama Basin; Pleistocene; Productivity; Quaternary; Stable isotopes; Upper Pleistocene
Coordinates: N000100 N000100 W0822800 W0822800
N075100 N075100 W0833600 W0833600
Record ID: 2010081939
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