Sensitivity of clumped isotope temperatures in fossil benthic and planktic Foraminifera to diagenetic alteration

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doi: 10.1016/j.gca.2019.05.005
Author(s): Leutert, Thomas J.; Sexton, Philip F.; Tripati, Aradhna; Piasecki, Alison; Ho, Sze Ling; Meckler, A. Nele
Author Affiliation(s): Primary:
University of Bergen, Bjerknes Centre for Climate Research and Department of Earth Science, Bergen, Norway
Open University, United Kingdom
University of California, United States
Université de Brest, France
Harvard University, United States
National Taiwan University, Taiwan
Volume Title: Geochimica et Cosmochimica Acta
Source: Geochimica et Cosmochimica Acta, Vol.257, p.354-372. Publisher: Elsevier, New York, NY, International. ISSN: 0016-7037 CODEN: GCACAK
Note: In English. 86 refs.; illus., incl. 2 tables, sketch map
Summary: Applying the clumped isotope (Δ47) thermometer to foraminifer microfossils offers the potential to significantly improve paleoclimate reconstructions, owing to its insensitivity to the isotopic composition of seawater (unlike traditional oxygen isotope (δ18O) analyses). However, the extent to which primary Δ47 signatures of foraminiferal calcites can be altered during diagenesis is not well known. Here, we present Δ47 data as well as high-resolution (∼10 kyr) δ18O and δ13C middle Eocene time series, measured on benthic and planktic foraminifera from ODP/IODP Sites 1408, 1409, 1410, 1050, 1260 and 1263 in the Atlantic Ocean. The sites examined span various oceanographic regimes, including the western tropical to mid-latitude North Atlantic, and the eastern mid-latitude South Atlantic. Comparing data from contemporaneous foraminifera with different preservation states, we test the effects of diagenetic alteration on paleotemperature reconstructions for the deep and surface ocean. We find that overall, primary Δ47 signatures appear similarly sensitive to diagenetic overprinting as δ18O, with differences in sensitivity depending on pore fluid chemistry and the amount of secondary calcite. Where planktic foraminifera are significantly altered, sea surface temperatures derived from Δ47 and δ18O values are biased towards cool temperatures. In comparison, Δ47 and δ18O values of benthic and well preserved planktic foraminifera are less affected by diagenesis and thus likely to yield robust foraminiferal calcification temperatures. With independent estimates of diagenetic calcite fractions, secondary overprints could be corrected for, using end-member modeling and Δ47-based temperatures from benthic foraminifera.
Year of Publication: 2019
Research Program: IODP Integrated Ocean Drilling Program
ODP Ocean Drilling Program
Key Words: 02 Geochemistry; 12 Stratigraphy, Historical Geology and Paleoecology; Alteration; Atlantic Ocean; Benthic taxa; Biostratigraphy; Blake Nose; Blake Plateau; C-13/C-12; Calcite; Carbon; Carbonates; Cenozoic; Demerara Rise; Diagenesis; Eocene; Equatorial Atlantic; Expedition 342; Foraminifera; Fossils; Geochemistry; IODP Site U1408; IODP Site U1409; Integrated Ocean Drilling Program; Isotope ratios; Isotopes; Leg 171B; Leg 207; Leg 208; Microfossils; North Atlantic; Northwest Atlantic; O-18/O-16; ODP Site 1050; ODP Site 1260; ODP Site 1263; Ocean Drilling Program; Oxygen; Paleoclimatology; Paleogene; Paleotemperature; Planktonic taxa; Reconstruction; Sensitivity analysis; South Atlantic; Stable isotopes; Tertiary; Walvis Ridge; West Atlantic
Record ID: 2019055881
Copyright Information: GeoRef, Copyright 2019 American Geosciences Institute. Reference includes data from CAPCAS, Elsevier Scientific Publishers, Amsterdam, Netherlands

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